Product ID:PREMIUM UNLEADED GASOLINE ULT10340
MSDS Date:07/10/1991
FSC:9130
NIIN:00-148-7104
MSDS Number: BPPKH

ULTRAMAR, INC.

LONG BEACH, CA 90809-3102
US

Emergency Phone: 213-491-6795/213-435-5832

Info Phone: 213-491-6795/213-435-5832

Cage: KO292

ULTRAMAR, INC.

93102 LONG BEACH, CA 90809-3102 US

Telephone: 213-491-6795/213-435-5832

Cage: KO292

GASOLINE

CAS: 8006-61-9

RTECS: LX3300000

Fraction By Weight: >99%

OSHA PEL 300 PPM/500 STEL

ACGIH TLV: 300 PPM/500STEL;9293

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: >0.1%

OSHA PEL 1PPM/5STEL;1910.1028

ACGIH TLV: 10 PPM; A2; 9293

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

LD50 LC50 Mixture:LD50 ORAL RAT IS 18000 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE: IRRITATION, CENTRAL NERVOUS
SYSTEM EFFECTS. GASOLINE IF SWALLOWED, MAY BE ASPIRATED INTO LUNGS,
RESULTING IN PULMONARY EDEMA AND CHEMICAL PNEUMONITIS. CHRONIC:
BENZENE IS A CONFIRMED CARCINOGEN AND MAY PRODUCE BLOOD CHANGES.
PROLONGED EXPOSURE TO HIGH CONCENTRATIONS HAS CAUSED KIDNEY AND
LIVER CANCER IN RAT/MICE
Explanation of Carcinogenicity:BENZENE IS A CONFIRMED CARCINOGEN BY
NTP, IARC AND OSHA.
Effects of Overexposure:EYES/SKIN: SLIGHT IRRITATION. INHALATION:
HEADACHE, NAUSEA, WEAKNESS, SEDATION, AND UNCONSCIOUSNESS.
INGESTION: IRRITATION AND BURNING SENSATION WITH NAUSEA, VOMITING
AND DIARRHEA.
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH A HISTORY OF SKIN,
RESPIRATORY OR CENTRAL NERVOUS SYSTEM DISORDERS MAY BE AT INCREASED
RISK FROM EXPOSURE.

First Aid:EYES: FLUSH WITH PLENTY OF WATER FOR 15 MINUTES.SEE DOCTOR.
SKIN: REMOVE CONTAMINATED CLOTHING AND SHOES. WASH WITH SOAP AND
WATER.SEE DOCTOR. INHALATION: REMOVE VICTIM TO FRESH AIR.GIVE
OXYGEN/CPR IF NEEDED.SEE DOCTOR. INGESTION: DO NOT INDUCE
VOMITING.SEE DOCTOR IMMEDIATELY. *** NOTE TO PHYSICIAN: GASTRIC
LAVAGE USING CUFFED ENDOTRACHEAL TUBE MAY BE PERFORMED AT YOUR
DISCRETION ***

Flash Point Method:TCC
Flash Point:-45F,-43C
Autoignition Temp:Autoignition Temp Text:536F
Lower Limits:1.2
Upper Limits:7.6
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL. DO NOT USE SOLID WATER STREAM, IT MAY SPREAD THE FIRE.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED
CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:EXTREMELY FLAMMABLE. VAPORS CAN TRAVEL A
LONG DISTANCE ALONG GROUND AND FLASHBACK EXPLOSIVELY. CONTAINERS
MAY VIOLENTLY RUPTURE IN HEAT OF FIRE.

Spill Release Procedures:ELIMINATE IGNITION SOURCES. STOP LEAK IF
POSSIBLE. USE WATER SPRAY TO REDUCE VAPORS. TAKE UP SMALL SPILLS
WITH ABSORBENT AND PLACE IN CONTAINERS. FOR LARGER SPILLS, DIKE FOR
LATER DISPOSAL. KEEP PEOPL E AWAY. ISOLATE AREA AND RESTRICT ENTRY.
Neutralizing Agent:NOT APPLICABLE.

Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED
PLACE,AWAY FROM HEAT,IGNITION SOURCES AND INCOMPATIBLE
MATERIALS.KEEP CONTAINERS CLOSED WHEN NOT IN USE.
Other Precautions:AVOID BREATHING VAPORS, AND EYE AND SKIN CONTACT. USE
ONLY WITH ADEQUATE VENTILATION. DO NOT SIPHON BY MOUTH. BOND AND
GROUND CONTAINERS DURING TRANSFER. PROTECT CONTAINERS FROM PHYSICAL
DAMAGE.

Respiratory Protection:NIOSH/MSHA RESPIRATOR WITH ORGANIC VAPOR
CARTRIDGE APPROPIATE FOR EXPOSURE OF CONCERN OR SCBA IF TLV IS
EXCEEDED.
Ventilation:SUFFICIENT MECHANICAL (GENERAL) AND/OR LOCAL EXHAUST
VENTILATION. USE EXPLOSION-PROOF EQUIPMENT.
Protective Gloves:VITON, NITRILE, PVA.
Eye Protection:SPLASH-PROOF GOGGLES.
Other Protective Equipment:FULL BODY LONG-SLEEVED GARMENTS TO PREVENT
REPEATED OR PROLONGED SKIN CONTACT. EYE WASH STATION AND SAFETY
SHOWER.
Work Hygienic Practices:AVOID CONTACT WITH EYES AND SKIN. DO NOT
BREATHE VAPORS. WASH THOROUGHLY AFTER HANDLING. LAUNDER
CONTAMINATED CLOTHING.
Supplemental Safety and Health
THESE PRECAUTIONS ARE FOR NORMAL USES AND CONDITIONS. WHERE SPECIAL OR
UNUSUAL CONDITIONS EXIST, CONSULT AN INDUSTRIAL HYGIENIST.

HCC:F2
Boiling Pt:B.P. Text:100F,38C
Vapor Density:>1
Spec Gravity:0.7-0.8
pH:3-4
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR, COLORLESS TO AMBER, AROMATIC, VOLATILE
LIQUID.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, HALOGENS, STRONG ACIDS AND ALKALIES.
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
OF IGNITION
Hazardous Decomposition Products:CARBON OXIDES AND VARIOUS HYDROCARBONS
WHEN BURNED.

Waste Disposal Methods:CONSULT YOUR LOCAL ENVIRONMENTAL OFFICER. HMIS
RECOMMENDS INCINERATION OR TRANSFER TO RCRA PERMITTED WASTE
MANAGEMENT FACILITY. DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE AND LOCAL EN VIRONMENTAL REGULATIONS. EPA WASTE
CODED001.

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.